Luminescent properties of europium (III) acetate monohydrate in synthetic opal pores

Abstract

This paper presents a systematic photoluminescence spectra study of the (111) growth surface of an opal photonic crystal whose pores were filled with salt Europium (III) acetate monohydrate (C₆H₉EuO₆×H₂O). Ultraviolet excitation was provided by semiconductor laser operating at wavelengths of 405?nm. Emission spectra were measured both for free-form salt samples and for salt in opal pores annealed at various temperatures up to 1000?°C. The influence of changes in the coordination environment of europium ions on the luminescence spectra in the process of dehydration and salt decomposition up to Eu₂O₃ is established. Differences in the spectra of salt in the pores of opal were revealed compared with the spectra in the free state.     

Water distribution in multilayers of weak polyelectrolytes

The water localization in thin polyelectrolyte multilayers assembled from poly(acrylic acid) and poly(allylamine hydrochloride) was investigated with neutron reflectivity in an atmosphere of controlled humidity and with bulk water. Water was found to be distributed asymmetrically within the multilayer and to localize preferentially at the polymer surface. The diffusion of water into the multilayer did not completely penetrate to the substrate, but instead there appeared to be an exclusion zone near the Si substrate. These results help to explain previous observations of anomalous water transport kinetics in weak polyelectrolyte systems.     

DSC TOPEM® study of high-energy mechanical milling-driven amorphization in β-As4S4-based arsenicals

Journal of Thermal Analysis and Calorimetry - Temperature-modulated DSC TOPEM® method was applied to study amorphization in directly synthesized high-temperature polymorph of tetra-arsenic...     

Hardy type spaces associated with compact unitary groups

We investigate Hilbertian Hardy type spaces of complex analytic functions of infinite many variables, associated with compact unitary groups and the corresponding invariant Haar’s measures. For such analytic functions we establish a Cauchy type integral formula and describe natural domains. Also we show some relations between constructed spaces of analytic functions and the symmetric Fock space.     

Regio- and stereoselectivity of polar [2+3] cycloaddition reactions between (Z)-C-(3,4,5-trimethoxyphenyl)-N-methylnitrone and selected (E)-2-substituted nitroethenes

[2+3] Cycloaddition reactions of the highly reactive (Z)-C-(3,4,5-trimethoxyphenyl)-N-methylnitrone with (E)-2-R-nitroethenes proceed under mild conditions and yield mixtures of stereoisomeric 2-methyl-3-(3,4,5-trimethoxyphenyl)-4-nitro-5-R-isoxazolidines. The effect of regiospecificity of the cycloadditions may be accounted for by the theory of electrophilicity indexes. Stereoselectivity, however, is determined by a compilation of steric and secondary orbital effects.      

Chimera states: the natural link between coherence and incoherence

Chimera states are remarkable spatiotemporal patterns in which coherence coexists with incoherence. As yet, chimera states have been considered as nongeneric, since they emerge only for particular initial conditions. In contrast, we show here that in a network of globally coupled oscillators delayed feedback stimulation with realistic (i.e., spatially decaying) stimulation profile generically induces chimera states. Intriguingly, a bifurcation analysis reveals that these chimera states are the natural link between the coherent and the incoherent states.     

Manifestations of sub- and superluminality in filamented femtosecond laser pulse in fused silica

Filamented propagation of femtosecond laser pulses in fused silica is studied using microscopy of Femtosecond Time-resolved Optical Polarigraphy (FTOP). Both super- and subluminal translation of axial intensity maxima in a 100 fs time scale has been directly recorded. The observed spatio-temporal periodicity of the pulse shape in longitudinal and transversal directions is tentatively interpreted as two projections on X and Y axes of the same fringe pattern formed by the interference of the axial part of the beam and spontaneously generated conical beam.     

The peculiarities of homogeneous nucleation of reactive Cu0 colloidal particles in the presence of functional oligoperoxides

A method is proposed that combines the stage of formation of colloidal metal and metal-oxide particles with the stage of their surface modification by functional surface-active oligoperoxides (FSAP), which are sorbed irreversibly. Investigation of copper particle homogeneous nucleation kinetics witnesses the significant influence of supermolecular micelle-like structures formed by FSAP in solution on the reduction rate of Cu2+ cations caused by a phenomenon analogous to micellar catalysis. The rate constants of copper reduction in different local zones of the process have been determined. Particle homogeneous nucleation kinetics in the presence of surface-active oligoperoxides has been found to correspond to the main regularities of the Michaelis-Menten equation describing micellar catalysis. The carrying out of copper particle formation in distinct zones correlates well with the particle size distribution. The presence of reactive ditertiary peroxidic fragments on the particle surface as a result of FSAP sorption confers reliable protection from oxidation, hydrophobicity, and ability to form free radicals and participate in elementary stages of radical processes.